تخليق و تشخيص معقدات القصدير العضوية الثلاثية – تايروسين ودراسة تطبيقاتها كمؤكسدات بطريقتي  DPPH  CUPRAC

المؤلفون

  • رافد ريس عراك قسم الكيمياء، كلية العلوم، جامعة بابل، بابل، العراق.
  • أنغام غانم هادي قسم الكيمياء، كلية العلوم، جامعة بابل، بابل، العراق. https://orcid.org/0000-0002-5396-7560

DOI:

https://doi.org/10.21123/bsj.2024.9043

الكلمات المفتاحية:

Antioxidant activity, Condensation reaction, CUPRAC method, Triorganotin (IV) complexes, Tyrosine.

الملخص

من خلال تفاعلات التكثيف بين التايروسين (ليكاند) واملاح القصدير الثلاثية العضوية في وجود هيدروكسيد الصوديوم، تم تخليق ثلاثة معقدات ثلاثية عضوية للقصدير- تايروسين بنجاح. وتم إذابة جميع المكونات في الميثانول والتصعيد لمدة خمس ساعات. تم تشخيص المعقدات الناتجة بجهازتحليل العناصر(CHN).واستخدم التحليل الطيفي بالأشعة تحت الحمراء والتحليل الطيفي للرنين المغناطيسي النووي ( 119Sn-NMR , 13C 1H,  ). بناءً على قياسات الطيف، تم تعيين هندسة ثثنائية الهرم المثلثي للمعقدات الناتجة بنسبة منتوج تتراوح بين 85-97٪. تم استخدام طرق DPPH و CUPRAC، لأختبار النشاط المضاد للأكسدة لمعقدات التايروسين الثلاثي . بسبب وجود الشق الفلزي، كان للمركبات العضوية (IV) نشاط مضاد للأكسدة أكثر من الليكاند في حين أظهر مركب ثلاثي ميثيل القصدير (IV) مستوى أعلى في النشاط المضاد للأكسدة من المعقدات الأخرى.

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كيفية الاقتباس

1.
تخليق و تشخيص معقدات القصدير العضوية الثلاثية – تايروسين ودراسة تطبيقاتها كمؤكسدات بطريقتي  DPPH  CUPRAC. Baghdad Sci.J [انترنت]. [وثق 18 مايو، 2024];21(11). موجود في: https://www.bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/9043