تحضير وتشخيص ودراسة صناعية وبايولوجية لليكاند صبغة الآزو وبعض أيوناتة الفلزية
DOI:
https://doi.org/10.21123/bsj.2024.8319الكلمات المفتاحية:
اصباغ الآزو ، الفعالية البايولوجية ،4-امينوانتيبيرين، معقدات العناصر، الخيوط الصناعية.الملخص
حضر4-((2-هيدروكسي-3،5- ثنائي نيترو) دايازنيل) 1،5-ثنائي مثيل- 2-فنيل-1بايرازول-3-((2H-اون من مفاعلة ملح الدايازونيوم للمركب 4-امينو انتي بايرين مع 2،4- ثنائي نيتروفينول. تم تشخيص الليكاند بوساطة طيف الأشعة فوق البنفسجية- المرئية والأشعة تحت الحمراء وطيف الرنين النووي المغناطيسي للبروتون والكاربون وطيف الكتلة ، فضلا عن قياس التحليل الدقيق للعناصر(C.H.N.O) . حضرت معقدات الكوبلت (II) والنيكل (II)والنحاس(II) والخارصين(II) وشخصت بوساطة تقنية الامتصاص الذري اللهبي واطياف الأشعة فوق البنفسجية- المرئية والأشعة تحت الحمراء والتحليل الدقيق للعناصر(C.H.N.O)، فضلا عن قياسات التوصيلية المولارية والحساسية المغناطيسية. درست تراكيب المعقدات باستخدام طريقتي النسب المولية والمتغيرات المستمرة، وخضعت محاليل هذه المعقدات لقانون لامبرت – بير ضمن مدى التراكيز - 3×10-4 M ) 10×1)، اشارة النتائج التحليلية ان نسبة فلز: ليكاند هي (1:2). ومن خلال النتائج التحليلية تم اقتراح الشكل ثماني السطوح للمركبات المحضرة ، كما تم اختبار المركبات المحضرة للدراسات الصناعية والبايولوجية.
Received 03/01/2023,
Revised 04/08/2023,
Accepted 06/08/2023,
Published Online First 20/03/2024
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الحقوق الفكرية (c) 2024 Abaas Obaid Hussein , Rana Abdulilah Abbas , Jinan M. M. Al-Zinkee , AmerJ. Jarad
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